Chargée de Recherches

E-mail : bolvin.at.irsamc.ups-tlse.fr
Address : LCPQ-IRSAMC,
118 Route de Narbonne,
31062 Toulouse Cedex 4, France
Office : 222 Bâtiment 3R1B4
Phone : +33 (0)5 61 55 64 67
Fax : +33 (0)5 61 55 60 65

 Theoretical description of the magnetic susceptibility and the UV-vis spectra of An(III) and An(IV) aquo complexes

 Orbital model for the Zero Field Splitting in octahedral Ni(II) complexes

 Magnetic and hysteresis coupling in a Dy(III) dimer

 Hyperfine coupling and hysteresis in a Ho(III) dimer

 Spin Hamiltonians from S=1/2 up to S=5/2

Short CV

Since 2010 : Laboratoire de Chimie et Physique Quantiques, Université Paul Sabatier, Toulouse, France.
2001 - 2010 : Laboratoire de Chimie Quantique, Université de Strasbourg, France.
1999 - 2001 : Institutt for kjemi, Universitetet i Tromso, Norway
1993 - 1999 :
Laboratoire de Physique Quantiques, Université Paul Sabatier, Toulouse, France.
1989 - 1993 : PhD in Chemistry in the [Laboratoire de Chimie Inorganique] Université d’Orsay, France , under the supervision of Olivier Kahn.

 Paramagnetism of Aqueous Actinide Cations. Part II : Theoretical aspects and new measurements on An(IV)
M. Autillo, L. Guerin, D. Guillaumont, P. Moisy, H. Bolvin, C. Berthon Inorg. Chem. 55, 12149-12157 (2016).
 Unraveling and effects on the magnetic anisotropy in cis-NiA₄B₂ complexes : magnetization, HF-HFEPR studies, first principles calculations and orbital model.
G. Charron, E. Malkin, G. Rogez, L. J. Batchelor, S. Mazerat, R. Guillot, N. Guihéry, A. L. Barra, T. Mallah, H. Bolvin Chem. Eur. J. 22 16848-16860 (2016).
 Relativistic methods for calculating Electron Paramagnetic Resonance (EPR) parameters
H. Bolvin, J. Autschbach in Liu, W. (editor), ‘Handbook of Relativistic Quantum Chemistry’, Springer, Berlin (2016).
 Assessing the exchange coupling in binuclear lanthanide(III) complexes and the slow relaxation of the magnetization in the antiferromagnetically coupled Dy₂
derivative
C. Y. Chow, H. Bolvin, V. E. Campbell, R. Guillot, J. W. Kampf, W. Wernsdorfer, F. Gendron, J. Autschbach, V. L. Pecoraro, T. Mallah Chem. Sci., 6, 4148 - 4159, (2015).
 Magnetic properties and electronic structure of neptunyl(VI) complexes : Wavefunctions, orbitals, and crystal-field models
F. Gendron, D. Paez Hernandez, F. P. Notter, B. Pritchard, H. Bolvin, J. Autschbach Chem. Eur. J. 20, 7994 (2014).